(Z)-3-Ferrocenyl-2-(4-pyridyl)propenenitrile
نویسندگان
چکیده
In the title compound, [Fe(C(5)H(5))(C(13)H(9)N(2))], the pyridine ring makes a dihedral angle of 9.91 (17)° with the substituted cyclo-penta-dienyl ring and the double bond adopts a Z configuration. In the crystal structure, inter-molecular C-H⋯N hydrogen bonds link the molecules into a one-dimensional chain in the a+c direction.
منابع مشابه
(4′-Ferrocenyl-2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)(1,10-phenanthroline-κ2 N,N′)copper(II) bis(perchlorate) acetonitrile solvate
The title complex, [CuFe(C(5)H(5))(C(20)H(14)N(3))(C(12)H(8)N(2))](ClO(4))(2)·C(2)H(3)N, consists of a mononuclear [Cu(C(12)H(8)N(2))(C(25)H(19)FeN(3))](2+) cation, two ClO(4) (-) anions (one of which is disordered over two positions with equal occupancy) and one CH(3)CN solvent mol-ecule. The Cu(II) center has a distorted square-pyramidal coordination with three N atoms of the 4'-ferrocenyl-2,...
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In the title complex, [FeZn(C(5)H(5))(C(20)H(14)N(3))(C(12)H(8)N(2))](ClO(4))(2)·CH(3)CN, the Zn(II) atom is five-coordinated by a tridentate chelating 4'-ferrocenyl-2,2':6',2''-terpyridine (fctpy) ligand and a bidentate chelating 1,10-phenanthroline (phen) ligand in a distorted square-pyramidal environment with a phen N atom located at the apical position [Zn-N = 2.259 (4) Å]. The terpyridyl m...
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The synthesis of heterocyclic thioureas from heterocyclic amines with phenylor methylisothiocyanate or CS2 is described. Seven new X-ray crystal structures are reported: In N-(3-pyridyl)-N0-phenylthiourea (Pna21, a = 10.1453(3), b = 17.6183(5), c = 6.4787(2), V = 1158.02(6), Z = 4) hydrogen-bonding results in formation of a 3D network consisting of helices, which form channels parallel to the c...
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In the title coordination polymer, {[FeMn(C(5)H(5))(C(13)H(7)O(4))(C(10)H(9)N(3))(H(2)O)]·CH(3)OH·H(2)O}(n), the Mn(II) ion has a distorted octa-hedral coordination geometry and is ligated by two N atoms from two di-2-pyridyl-amine mol-ecules, three O atoms from two 5-ferrocenyl-benzene-1,3-dicarboxyl-ate anions and one O atom from a coordinated water mol-ecule. The Mn-O distances range from 2....
متن کامل2-Ferrocenyl-3-methoxy-6-methylpyridine
In the title compound, [Fe(C(5)H(5))(C(12)H(12)NO)], the dihedral angle between the pyridyl and substituted cyclo-penta-dienyl rings is 23.58 (3)°. The crystal structure is characterized by weak inter-molecular C-H⋯N hydrogen-bonding contacts, leading to the formation of chains running parallel to the n-glide planes. A weak inter-molecular C-H⋯π contact is also present.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008